| Jornada 1 | 27-08-2006 | ALAVES | 1 | ELCHE | 1 |
| Jornada 2 | 03-09-2006 | MALAGA | 1 | ALAVES | 0 |
| Jornada 3 | 10-09-2006 | ALAVES | 3 | REAL MADRID B | 1 |
| Jornada 4 | 17-09-2006 | VECINDARIO | 0 | ALAVES | 1 |
| Jornada 5 | 24-09-2006 | ALAVES | 0 | TENERIFE | 0 |
| Jornada 6 | 01-10-2006 | MURCIA | 1 | ALAVES | 0 |
| Jornada 7 | 08-10-2006 | ALAVES | 1 | ALMERIA | 0 |
| Jornada 8 | 15-10-2006 | CADIZ | 1 | ALAVES | 1 |
| Jornada 9 | 22-10-2006 | ALAVES | 2 | CASTELLON | 0 |
| Jornada 10 | 29-10-2006 | HERCULES | 3 | ALAVES | 1 |
| Jornada 11 | 05-11-2006 | SALAMANCA | 3 | ALAVES | 0 |
| Jornada 12 | 12-11-2006 | ALAVES | 1 | ALBACETE | 1 |
| Jornada 13 | 19-11-2006 | NUMANCIA | 1 | ALAVES | 1 |
| Jornada 14 | 26-11-2006 | ALAVES | 0 | SPORTING GIJON | 0 |
| Jornada 15 | 03-12-2006 | LAS PALMAS | 6 | ALAVES | 1 |
| Jornada 16 | 10-12-2006 | ALAVES | 1 | CIUDAD MURCIA | 0 |
| Jornada 17 | 17-12-2006 | POLI.EJIDO | 5 | ALAVES | 2 |
| Jornada 18 | 20-12-2006 | ALAVES | 1 | XEREZ | 0 |
| Jornada 19 | 07-01-2007 | VALLADOLID | 1 | ALAVES | 0 |
| Jornada 20 | 14-01-2007 | ALAVES | 3 | LORCA | 1 |
| Jornada 21 | 21-01-2007 | PONFERRADINA | 0 | ALAVES | 2 |
| Jornada 22 | 28-01-2007 | ELCHE | 1 | ALAVES | 0 |
| Jornada 23 | 04-02-2007 | ALAVES | 0 | MALAGA | 1 |
| Jornada 24 | 11-02-2007 | REAL MADRID B | 1 | ALAVES | 1 |
| Jornada 25 | 18-02-2007 | ALAVES | 5 | VECINDARIO | 1 |
| Jornada 26 | 25-02-2007 | TENERIFE | 1 | ALAVES | 2 |
| Jornada 27 | 04-03-2007 | ALAVES | 1 | MURCIA | 1 |
| Jornada 28 | 11-03-2007 | ALMERIA | 2 | ALAVES | 2 |
| Jornada 29 | 18-03-2007 | ALAVES | 1 | CADIZ | 1 |
| Jornada 30 | 25-03-2007 | CASTELLON | 2 | ALAVES | 0 |
| Jornada 31 | 01-04-2007 | ALAVES | 2 | HERCULES | 3 |
| Jornada 32 | 08-04-2007 | ALAVES | 0 | SALAMANCA | 2 |
| Jornada 33 | 15-04-2007 | ALBACETE | 2 | ALAVES | 2 |
| Jornada 34 | 22-04-2007 | ALAVES | 2 | NUMANCIA | 2 |
| Jornada 35 | 29-04-2007 | SPORTING GIJON | 1 | ALAVES | 1 |
| Jornada 36 | 06-05-2007 | ALAVES | 1 | LAS PALMAS | 2 |
| Jornada 37 | 13-05-2007 | CIUDAD MURCIA | 5 | ALAVES | 1 |
| Jornada 38 | 20-05-2007 | ALAVES | 2 | POLI.EJIDO | 1 |
| Jornada 39 | 27-05-2007 | XEREZ | 0 | ALAVES | 2 |
| Jornada 40 | 03-06-2007 | ALAVES | 1 | VALLADOLID | 2 |
| Jornada 41 | 10-06-2007 | LORCA | 1 | ALAVES | 2 |
| Jornada 42 | 17-06-2007 | ALAVES | 1 | PONFERRADINA | 2 |